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R Švejkar, J Šulc, M Němec, H Jelínková… – SPIE LASE, 2016

The laser and spectroscopic properties of crystal Er,La:SrF2-CaF2 at temperature range 80 – 300 K, which is appropriate for generation of radiation around 2.7 um is presented. The sample of Er,La:SrF2-CaF2 (concentration Er(0.04), La(0.12):Ca(0.77)Sr(0.07)) had plan-parallel face-polished faces without anti-reflection coatings (thickness 8.2 mm). During spectroscopy and laser experiments the Er,La:SrF2-CaF2 was attached to temperature controlled copper holder and it was placed in vacuum chamber. The transmission and emission spectra of Er,La:SrF2-CaF2 together with the fluorescence decay time were measured in dependence on temperature. The excitation of Er,La:SrF2-CaF2 was carried out by a laser diode radiation (pulse duration 5 ms, repetition rate 20 Hz, pump wavelength 973 nm). Laser resonator was hemispherical, 140 mm in length with at pumping mirror (HR @ 2.7 µm) and spherical output coupler (r = 150 mm, R = 95 % @ 2.5 – 2.8 µm). Tunability of laser at 80 K in range 2690 – 2765 nm was obtained using MgF2birefringent filter. With decreasing temperature of sample the fluorescence lifetime of manifold 4I11/2 (upper laser level) became shorter and intensity of up-conversion radiation was increasing. The highest slope efficiency with respect to absorbed power was 2.3 % at 80 K. The maximum output of peak amplitude power was 0.3 W at 80 K, i.e. 1.5 times higher than measured this value at 300 K. The wavelength generated by Er,La:SrF2-CaF2laser (2.7 µm) is relatively close to absorption peak of water (3 µm) and so, one of the possible usage should be in medicine and spectroscopy.

ultraviolet, and ±0.8 nm in mid-infrared. Fluorescence spectra were measured by
fibre spectrometer StellarNet BlueWave NIR50 (500 – 1050 nm). Laser emission radiation 2.7 im was

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