Antonietta Mancuso, Wanda Navarra, Olga Sacco, Stefania Pragliola, Vincenzo Vaiano and Vincenzo Venditto
Abstract
Different tri-doped TiO2 photocatalysts (Fe-N-P/TiO2 , Fe-N-S/TiO2 , Fe-Pr-N/TiO2 , PrN-S/TiO2 , and P-N-S/TiO2 ) were successfully prepared and tested in the photocatalytic removal of thiacloprid (THI) under UV-A, visible, and direct solar light irradiation. The physical-chemical properties of the prepared catalysts were analyzed by different characterization techniques, revealing that dopants are effectively incorporated into the anatase TiO2 lattice, resulting in a decrease of the energy band gap. The reduction of photoluminescence intensity indicates a lower combination rate and longer lifespan of photogenerated carriers of all doped samples in comparison with the un-doped TiO2 . The doped photocatalysts not only significantly promote the photodegradation under UV-A light irradiation but also extend the optical response of TiO2 to visible light region, and consequently improve the visible light degradation of THI. Fe-N-P tri-doped TiO2 sample exhibits the highest THI photodegradation degree (64% under UV-A light, 29% under visible light and 73% under solar light).
